Different ionic compounds can release the same ions into solution. This ultimately means that different ionic compounds can affect the equilibrium of other ionic compounds.
Common ion effect: The solubility of a salt can be reduced by the presence of another salt that has a common ion.
Example: if NaCl is dissolved and HCl(aq) is added to the solution. This introduces chlorine ions and forces the equilibrium to the left due to Le Châtelier’s Principle, producing more NaCl(s).
Practice: If KBr is added to a solution containing PbBr2(aq), will more PbBr2 solidify? Yes
If KBr is added to a solution containing NaCl, will more NaCl precipitate? No, no common ion
Example: How many moles of PbCl2(s) will dissolve in 1L of 0.2M NaCl at SATP?
Common ion = Cl-1
Since there are no lead ions to start, Q=0 and the rxn shifts to the right
I – 0 0.2
C – +x +2x
E – x 0.2+2x
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